What are Molecular Sieves Used For?
As the European Union tries to reduce its dependence on Russian energy, the Russian president recently said Russia would try to shift its energy exports to the east, adding that there was no way for European countries to give up Russian gas immediately.
Russia supplies about 40 percent of the EU's gas, and western sanctions imposed over the conflict with Ukraine have complicated financing and logistical arrangements for existing agreements, hitting Russian energy exports, the report noted.
Russia has been building closer ties with China and other Asian countries as the European Union debates whether to impose sanctions on Russian gas and oil and member states seek supplies from elsewhere, Reuters said.
"So-called partners from unfriendly countries admit that they cannot survive without Russian energy, including gas," the Russian president said in a televised government meeting. There is no reasonable alternative to Russian gas in Europe right now."
He also said Europe was driving up energy prices and destabilizing markets by talking about cutting off Russia's energy supplies. Russia, which produces about a tenth of the world's oil and a fifth of its natural gas, will need new infrastructure to increase energy supplies to Asia, he said.
He ordered Moscow to submit a plan by June 1, including "the expansion of transport infrastructure to countries in Africa, Latin America, and the Asia-Pacific region".
He also sought to clarify the possibility of integrating two pipelines -- the Sakhalin-Khabarovsk-Vladivostok gas pipeline in the Far East and the "Power of Siberia" gas pipeline to China -- into Russia's unified gas supply system. In theory, connecting these routes to larger gas networks could allow Russia to divert gas from Europe to Asia.
Because of the ever-changing international situation, the supply and prices of international bulk molecular sieves are still very uncertain.
What are Molecular Sieves?
Molecular sieves are materials with holes of uniform size (very small holes). These pores are similar in size to small molecules, so large molecules cannot enter or be adsorbed, while smaller molecules can. As the molecular mixture migrates through a fixed bed of porous semi-solid material called a sieve (or matrix), the components with the highest molecular weight (unable to enter the molecular pore) first leave the bed and then pass through successive smaller molecules. Some zeolites are used in size-exclusion chromatography, a separation technique that sorts molecules by their size. Other molecular sieves are used as desiccants (some examples include activated carbon and silica gel).
The pore size of the molecular sieve is measured in angstrom (A) or nanometer (nm). According to IUPAC representation, the pore size of microporous materials is less than 2 nm (20 A), and that of macroporous materials is more than 50 nm (500 A). Thus, the mesoporous category is in the middle, with pore sizes ranging from 2 to 50 nm (20-500 A).
What are Molecular Sieves Used For?
Molecular sieves are commonly used in the petroleum industry, especially for drying airflow. For example, in the liquefied natural gas (LNG) industry, the water content of the gas needs to be reduced to less than 1ppmv to prevent clogging caused by ice or methane clathrates.
In the laboratory, molecular sieves are used to dry solvents. Sieves have proven superior to traditional drying techniques, which typically use corrosive desiccant.
Under the term zeolite, molecular sieves are used in a wide range of catalytic applications. They catalyze isomerization, alkylation, and epoxidation and are used in large-scale industrial processes, including hydrocracking and fluidization catalytic cracking.
They are also used to filter the air supply for breathing devices, such as those used by scuba divers and firefighters. In such applications, the air is supplied by an air compressor and passed through a cartridge filter, which is filled with molecular sieve and/or activated carbon, depending on the application, and is finally used to fill the breathing air tank. This filter removes particulates from the breathable air supply and compressor exhaust products.
Common types of molecular sieve:
3A molecular sieve:
The 3A molecular sieve does not adsorb molecules with diameters larger than 3 A. These molecular sieves are characterized by fast adsorption speed, frequent regeneration, good anti-breakage, and good anti-pollution. These features improve the efficiency and life of the sieve. 3A molecular sieve is a necessary desiccant for petroleum and chemical industry refining, polymerization, and chemical gas-liquid depth drying.
The 3A molecular sieve is used to dry a range of materials, such as ethanol, air, refrigerants, natural gas, and unsaturated hydrocarbons. The latter includes cracked gas, acetylene, ethylene, propylene, and butadiene.
The 3A molecular sieve is used to remove water from ethanol, which can then be used directly as a biofuel or indirectly to produce a variety of products, such as chemicals, food, medicines, and so on. Due to the formation of azeotropes with a concentration of about 95.6% (by weight), ordinary distillation cannot remove all water (unwanted byproducts in ethanol production) from the ethanol process stream, so molecular sieve beads are used to separate ethanol and water at the molecular level by the following method: Adsorbed water into the beads to allow ethanol to pass freely. Once the beads are filled with water, the temperature or pressure can be controlled to release the water from the molecular sieve beads.
4A molecular sieve:
4A molecular sieve is widely used in drying laboratory solvents. They can absorb water and other molecules with a critical diameter less than 4 A, such as NH3, H2S, SO2, CO2, etc. Widely used in liquid and gas drying, refining, and purification (such as the preparation of argon).
These molecular sieves are used as an aid to detergents because they can produce softened water through calcium ion exchange, removing and preventing dirt deposition. They are widely used as a substitute for phosphorus. 4A molecular sieve plays an important role in substituting sodium tripolyphosphate as a detergent additive to reduce the impact of detergent on the environment. It can also be used as a soap-forming agent and toothpaste.
Hazardous waste treatment
4A molecular sieve can purify ammonium ion, Pb2+, Cu2+, Zn2+, and Cd2+ cationic substances sewage. Due to their high selectivity to NH4 +, they have been successfully applied in this field to combat channel eutrophication and other effects caused by excess ammonium ions. Due to industrial activities, a 4A molecular sieve is also used to remove heavy metal ions present in water.
5A molecular sieve:
5A molecular sieves are commonly used in the petroleum industry, especially in the purification of airflow and in chemical laboratories for the separation of compounds and drying of reaction starting materials. They contain tiny pores of precise and uniform size and are used primarily as adsorbents for gases and liquids.
The 5A molecular sieve is used to dry natural gas and desulphurize and decarbonize the gas. They can also be used to separate mixtures of oxygen, nitrogen, and hydrogen, as well as oleowax hydrocarbons, from branched and polycyclic hydrocarbons.
What is molecular sieve adsorbent?
The molecular sieve adsorbent is a crystalline aluminum silicate, known as zeolite. Its unique structure allows the water of the crystal to be removed, leaving a porous crystalline structure. These pores or cages have a high affinity for reabsorbing water or other polar molecules.
Molecular Sieves Price
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Since February, gold has enjoyed a smooth upward run on the back of surging US inflation and the brewing of war. While expectations of rate rises have also risen in tandem over this period, gold had been largely pre-priced and the underlying driver of tightening expectations had come from inflation continuing to rise to record highs. The risk aversion caused by the continued tension in the war also provided an important short-term support for gold. This will have a certain impact on the price of the molecular sieves and the market of the molecular sieves.